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R404A Refrigerant Specification

Technical Data Sheet(TDS) R-404A(HFC blend) CHF₂CF₃ / CF₃CH₂F / CH₂FCF₃( 44/52/4) R404A, and.

Document No.:ZJ-TDS-R404A-2026 Version:V1.0 Issue date2026-09-24 Next review:2027-09-24

1 Product Identification

Item Value
Product NameR404A Refrigerant
Chemical NameR-404A(HFC blend)
English NameR-404A(HFC blend)
Molecular FormulaCHF₂CF₃ / CF₃CH₂F / CH₂FCF₃( 44/52/4)
Molecular Weight97.60
CAS Registry Number354-33-6 / 420-46-2 / 811-97-2
EINECS No.206-557-8 / 206-996-5 / 212-377-0
UN Number3337
Transport Hazard ClassClass 2.2, non-flammable gas
ASHRAE Safety ClassificationA1(Low toxicity, non-flammable)
Reference BasisManufacturer data; the batch COA governs

Reference Basis: Compiled from manufacturer data (safety classification per GB/T 7778, ASHRAE 34 / ISO 817)

2 Physical & Chemical Properties

R404A Typicaldata, system and,.

Item Typical Value
AppearanceColorless, transparent liquefied gas
OdorSlight ethereal odor, non-irritating
Bubble point(101.3 kPa)-46.5 ℃
(101.3 kPa)-45.7 ℃
Temperature glideapprox. 0.8 ℃(Near-azeotropic)
Critical Temperature72.1 ℃
Critical Pressure3.73 MPa
Critical Densityapprox. 485 kg/m³
Vapor Pressure (25 C, absolute)1.25 MPa
Liquid Density(25 ℃)1048 kg/m³
Saturated Vapor Density(25 ℃)47.5 kg/m³
Latent heat of vaporisation (at bubble point)approx. 200 kJ/kg
Liquid Specific Heat(25 ℃)1.53 kJ/(kg·K)
Vapor Specific Heat(25 ℃, 101.3 kPa)0.85 kJ/(kg·K)
Liquid Thermal Conductivity(25 ℃)0.084 W/(m·K)
Vapor Thermal Conductivity(25 ℃)0.0145 W/(m·K)
Liquid Viscosity(25 ℃)0.15 mPa·s
Vapor Viscosity(25 ℃)0.0132 mPa·s
Surface Tension(25 ℃)7.6 mN/m
Water Solubility(25 ℃)Slightly soluble
Auto-Ignition TemperatureNot applicable (non-flammable)
Flammability Limits in Air (vol.%)None (non-flammable)
OEL (8 h TWA)1000 ppm
Ozone Depletion Potential (ODP)0
GWP (100 yr, IPCC AR5)3922
Atmospheric Lifetimeapprox. 30 years(per)

3 Quality Specifications & Test Methods

R404A Parameter, Batch COA.

Item Parameter Test Method
AppearanceColourless and clear, free of suspended matter and mechanical impuritiesVisual inspection
Purity≥ 99.90 %Gas chromatography GC-FID
Composition toleranceR125 ±1.0 %, R143a ±1.0 %, R134a ±0.5 %Gas chromatography GC-FID
Moisture≤ 10 ppmKarl Fischer coulometric method
Acidity( HCl )≤ 0.1 ppmAlkali absorption - potentiometric titration
Evaporation Residue≤ 0.01 %Gravimetric method
Non-Condensable Gas(, 25 ℃)≤ 1.5 %Gas chromatography
(Cl⁻)Negative (pass)Silver nitrate turbidimetry

4 Comparison with Common Refrigerants

Comparison Item R404A(this product) R507 R452A
CompositionR125/R143a/R134a 44/52/4R125/R143a 50/50R32/R125/R1234yf 11/59/30
ODP000
GWP(100 years, AR5)392239851945
ASHRAE Safety ClassificationA1A1A1
Temperature glideapprox. 0.8 ℃0 ℃(Azeotropic)approx. 3 ℃
Typical evaporating temperature-45 ℃ ~ -30 ℃-45 ℃ ~ -30 ℃-45 ℃ ~ -30 ℃
Relative cooling capacityBaseline 100 %Slightly higher, approx. +2 % ~ +5 %and R404A
Compatible lubricantPOEPOEPOE
Retrofit feasibilityexisting installed baseLow temperaturesystem refrigerantand R404Alow-GWP Alternatives
Current selectionLow temperatureexisting installed baseLow temperaturesystemR404A low-GWP

5 Packaging Specifications

Package Type Specification Filling Ratio Valve Connection Application
disposable cylinder10.9 kg(customizable 9.5 kg)≤ 0.85 kg/LW21.8-14(customizable CGA / DIN)Servicing and small-batch use
steel cylinder400 kg(T )≤ 0.85 kg/LW21.8-14Bulk project supply
cylinder pallet12 × 10.9 kgPer cylinderW21.8-14Distribution via service networks
ISO ISO tankapprox. 18 tper ISO tankISO tankconnectionand Transport

Filling Ratioper"", steel cylinderper.

6 Applications

  • Low temperature cold storage and
  • and Transport
  • See the Technical Data Sheet (TDS) for full specifications.
  • and pharmaceuticalLow temperature

Equipment Compatibility & Charging Advice

  • R404A POE, systemper.
  • MainLow temperature, compressorperLow temperature refrigerantliquid injection or suction cooling, Discharge temperature.
  • charging, Temperature glide, charging.
  • R404A GWP 3922, EU F-Gas Regulationsnew equipmentrestricted, Item R452A, R448A or R449A.
  • recoveryrecoverysteel cylinder, and Other refrigerant,.

7 Storage & Transport

  • Storage,, ventilation, 40 ℃, ignition source, heat source and.
  • steel cylinder, and,,, and.
  • R404A Non-flammable, Vapour, Spillagelow-lying areasoxygen, ventilation.
  • and oxygen, and (,, )Flammable.
  • and, Low 0.05 MPa.
  • Transportper Danger 2.2 class, and, steel cylinder.

8 Safety & Handling

  • Asphyxiation riskVapour, Spillagelow-lying areas, and cold storageoxygen, ventilationoxygen(Low 19.5 %).
  • SpillageSpillageventilation,;;leak detection or leak detection, open flamesleak detection.
  • Thermal decomposition riskopen flames or High temperature(approx. 400 ℃ and above), cold storageventilation.
  • enclosedcold storage, enclosed confined space, oxygen.
  • frostbite ProtectionLiquefied gasfrostbite, and;frostbite 40 ℃.
  • Inhalation andVapourasphyxiation and, fresh airoxygen;Eye contact 15.

9 Quality Assurance & Shipping Documents

  • Batch COA, Purity( or ), Moisture, Acidity and Evaporation Residue.
  • Moisture, and Low temperature.
  • 12 months, Batch, No. and.
  • perthird-party test report(SGS / ), SDS Description REACH, RoHS.

10 Frequently Asked Questions

R404A and R507 Are they interchangeable?

Low temperature A1 refrigerant, R404A Temperature glideapprox. 0.8 ℃, R507 Azeotropic Mixture, and. compressor and, refrigerantrecoveryper refrigerantcharging,.

Why is R404A ?

R404A GWP 3922, "Kigali Amendment" and EU F-Gas Regulations phase-down, EUequipment GWP 2500 refrigerant. Item R452A(GWP 1945), R448A or R449A low-GWP Alternatives.

R404A What is the lowest evaporating temperature?

R404A Typicalapplication -45 ℃ ~ -30 ℃ Low temperature, or system, Low temperature cold storage and Transport. Low temperature( -60 ℃ and below)cascadesystem or R23 / R508B Ultra-low temperature refrigerant.

R404A Shelf life?

steel cylinder, Storage, R404A Shelf Life 24 months., steel cylinder and.

Disclaimer
Specificationdata Typical,;Parameter Batch COA. and, or or, equipment and Regulations.

| Reviewed by: | Approved by: | Hubei Zhongjin Fluorine Chemical Co., Ltd.

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