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R1234yf Refrigerant Specification

Technical Data Sheet(TDS) 2,3,3,3-Tetrafluoropropene(HFO-1234yf) CF₃CF=CH₂ R1234yf, and.

Document No.:ZJ-TDS-R1234YF-2026 Version:V1.0 Issue date2026-09-24 Next review:2027-09-24

1 Product Identification

Item Value
Product NameR1234yf Refrigerant
Chemical Name2,3,3,3-Tetrafluoropropene(HFO-1234yf)
English Name2,3,3,3-Tetrafluoropropene(HFO-1234yf)
Molecular FormulaCF₃CF=CH₂
Molecular Weight114.04
CAS Registry Number754-12-1
EINECS No.468-710-7
UN Number3163
Transport Hazard ClassClass 2.1, flammable gas
ASHRAE Safety ClassificationA2L(Low toxicity, mildly flammable)
Reference BasisManufacturer data; the batch COA governs

Reference Basis: Compiled from manufacturer data (safety classification per GB/T 7778, ASHRAE 34 / ISO 817)

2 Physical & Chemical Properties

R1234yf Typicaldata, system and,.

Item Typical Value
AppearanceColorless, transparent liquefied gas
OdorFaint, non-irritating
Boiling Point (101.3 kPa)-29.4 ℃
Freezing Point-150 ℃
Critical Temperature94.7 ℃
Critical Pressure3.38 MPa
Critical Densityapprox. 475 kg/m³
Vapor Pressure (25 C, absolute)0.674 MPa
Liquid Density(25 ℃)1092 kg/m³
Saturated Vapor Density(25 ℃)32.6 kg/m³
Latent Heat of Vaporization (at boiling point)approx. 180 kJ/kg
Liquid Specific Heat(25 ℃)1.39 kJ/(kg·K)
Vapor Specific Heat(25 ℃, 101.3 kPa)0.88 kJ/(kg·K)
Liquid Thermal Conductivity(25 ℃)0.075 W/(m·K)
Vapor Thermal Conductivity(25 ℃)0.0135 W/(m·K)
Liquid Viscosity(25 ℃)0.16 mPa·s
Vapor Viscosity(25 ℃)0.0118 mPa·s
Surface Tension(25 ℃)8.1 mN/m
Water Solubility(25 ℃)Slightly soluble
Auto-Ignition Temperature405 ℃
Flammability Limits in Air (vol.%)6.2 % ~ 12.3 %
Burning velocity≤ 10 cm/s(A2L)
OEL (8 h TWA)500 ppm
Ozone Depletion Potential (ODP)0
GWP (100 yr, IPCC AR5)< 1
Atmospheric Lifetimeapprox. 11

3 Quality Specifications & Test Methods

R1234yf Parameter, Batch COA.

Item Parameter Test Method
AppearanceColourless and clear, free of suspended matter and mechanical impuritiesVisual inspection
Purity≥ 99.90 %Gas chromatography GC-FID
Moisture≤ 10 ppmKarl Fischer coulometric method
Acidity( HF )≤ 0.1 ppmAlkali absorption - potentiometric titration
Evaporation Residue≤ 0.01 %Gravimetric method
Non-Condensable Gas(, 25 ℃)≤ 1.5 %Gas chromatography
Oxygen content in vapour phase≤ 0.05 %Gas chromatography
(Cl⁻)Negative (pass)Silver nitrate turbidimetry

4 Comparison with Common Refrigerants

Comparison Item R1234yf(this product) R134a R513A
CompositionSingle compound HFO-1234yfSingle compound CH₂FCF₃R1234yf/R134a 56/44
ODP000
GWP(100 years, AR5)< 11430573
ASHRAE Safety ClassificationA2L(Mildly flammable)A1A1
Boiling point-29.4 ℃-26.3 ℃-29.0 ℃
Relative cooling capacityapprox. 93 % ~ 98 %Baseline 100 %approx. 96 % ~ 100 %
Relative COPLow, approx. -2 % ~ -5 %Baselineand R134a
Compatible lubricantPOE / PVEPOEPOE
equipmentper A2L (Spillage, explosion-proof)Standard designR134a equipment
Current selectionair conditioning Regulationsand commercial refrigerationexisting installed baseR134a low-GWP

5 Packaging Specifications

Package Type Specification Filling Ratio Valve Connection Application
disposable cylinder10 kg(customizable 5 kg / 20 kg)≤ 0.95 kg/LW21.8-14(Dedicated connection)air conditioning Servicing and small-batch use
steel cylinder400 kg(T )≤ 0.95 kg/LDedicated connectionOEMsupply
cylinder pallet12 × 10 kgPer cylinderDedicated connectionserviceservice networkdistribution
ISO ISO tankapprox. 18 tper ISO tankISO tankconnectionand Transport

Filling Ratioper"", steel cylinderper.

6 Applications

  • passenger car and commercial vehicleair conditioningsystem
  • electric vehicleheat pump and battery thermal management
  • commercial refrigeration and Medium temperaturesystem(low-GWP Item)
  • chiller and air conditioning(per A2L )

Equipment Compatibility & Charging Advice

  • R1234yf A2L Mildly flammable refrigerant, equipmentper A2L: Spillage, ventilation and ignition sources, service A2L chargingrecovery equipment.
  • R1234yf and R134a, R134a system compressor, and equipment A2L.
  • POE or PVE, and;system and and R134a.
  • air conditioningchargingper, recovery equipment, emissions.
  • EU F-Gas Regulations GWP < 150 Spillage.

7 Storage & Transport

  • Storage,, ventilation, 40 ℃, ignition source, heat source and.
  • steel cylinder, and,,, and.
  • A2L Mildly flammable refrigerant, Flammable and ventilation, equipmentperexplosion-proof.
  • and oxygen, and (,, )Flammable.
  • and, Low 0.05 MPa.
  • Transportper Danger 2.1 class, Firefighting and, and.

8 Safety & Handling

  • Flammability and explosion riskR1234yf A2L Mildly flammable refrigerant, Flammability limit 6.2 % ~ 12.3 %, Burning velocity 10 cm/s, confined space SpillageFlammability and explosion risk, open flames, High temperature or sparks.
  • Spillageignition sourceventilation,;;leak detection or leak detection, open flamesleak detection.
  • Firefightingor carbon dioxide Firefighting, steel cylinder. Spillage Flame,.
  • Thermal decomposition riskopen flames or High temperature,, recovery refrigerantventilation.
  • frostbite ProtectionLiquefied gasfrostbite, and;frostbite 40 ℃.
  • Inhalation andVapourasphyxiation, and, fresh airoxygen;Eye contact 15.

9 Quality Assurance & Shipping Documents

  • Batch COA, Purity( or ), Moisture, Acidity and Evaporation Residue.
  • Moisture, and Low temperature.
  • 12 months, Batch, No. and.
  • perthird-party test report(SGS / ), SDS Description REACH, RoHS.

10 Frequently Asked Questions

R1234yf Can it directly replace R134a ?

. R1234yf A2L Mildly flammable refrigerant, Spillage and, R134a compressor, and equipment. serviceexisting installed base R134a, or EUper R1234yf.

Why is R1234yf GWP 1?

R1234yf,, Atmospheric Lifetimeapprox. 11, R134a approx. 14 years, years GWP 1, EU F-Gas Regulations(air conditioning GWP < 150) refrigerant.

R1234yf A2L What does it imply?

A2L Low toxicity, mildly flammable: Burning velocity 10 cm/s, A3 Propane, Isobutane, per Spillage, ventilation and ignition sources, service A2L charging, recovery and leak detection equipment.

R1234yf Shelf life?

steel cylinder, Storage, R1234yf Shelf Life 24 months., steel cylinder and.

Disclaimer
Specificationdata Typical,;Parameter Batch COA. and, or or, equipment and Regulations.

| Reviewed by: | Approved by: | Hubei Zhongjin Fluorine Chemical Co., Ltd.

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