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R31 Refrigerant Technical Data Sheet

Technical Data Sheet(TDS) Chlorofluoromethane CH₂ClF R31, and.

Document No.:ZJ-TDS-R31-2026 Version:V1.0 Issue date2026-09-24 Next review:2027-09-24

1 Product Identification

Item Value
Product NameR31 Refrigerant
Chemical NameChlorofluoromethane
English NameChlorofluoromethane
Molecular FormulaCH₂ClF
Molecular Weight68.49
CAS Registry Number593-70-4
EINECS No.209-803-2
UN Number3163(per Transport)
Transport Hazard ClassClass 2.2, non-flammable gas(per Transport)
ASHRAE Safety ClassificationASHRAE 34 class, per
Reference BasisManufacturer data; the batch COA governs

Reference Basis: (controlled, perquota)

2 Physical & Chemical Properties

R31 Typicaldata, system and,.

Item Typical Value
AppearanceColorless, transparent liquefied gas
OdorFaint ethereal odour
Boiling Point (101.3 kPa)-9.1 ℃
Freezing Pointapprox. -130 ℃
Critical Temperatureapprox. 178 ℃
Critical Pressureapprox. 5.3 MPa
Vapor Pressure (25 C, absolute)approx. 0.34 MPa
Liquid Density(25 ℃)approx. 1080 kg/m³
Latent Heat of Vaporization (at boiling point)approx. 300 kJ/kg
Liquid Specific Heat(25 ℃)approx. 1.35 kJ/(kg K)
Vapor Specific Heat(25 ℃, 101.3 kPa)approx. 0.70 kJ/(kg K)
Water Solubility(25 ℃)Slightly soluble
Auto-Ignition TemperatureNot applicable (non-flammable)
Flammability Limits in Air (vol.%)None (non-flammable)
Ozone Depletion Potential (ODP)approx. 0.02
Global warming potential (GWP) GWP(100 years)approx. 9
Atmospheric Lifetimeapprox. 1.4 years
Regulatory statusHCFC classcontrolled, perquota

3 Quality Specifications & Test Methods

R31 Parameter, Batch COA.

Item Parameter Test Method
AppearanceColourless and clear, free of suspended matter and mechanical impuritiesVisual inspection
Purity≥ 99.50 %Gas chromatography GC-FID
Moisture≤ 20 ppmKarl Fischer coulometric method
Acidity( HCl )≤ 0.2 ppmAlkali absorption - potentiometric titration
Evaporation Residue≤ 0.01 %Gravimetric method
Non-Condensable Gas(, 25 ℃)≤ 1.5 %Gas chromatography
(Cl⁻)perorderapprox.Silver nitrate turbidimetry

4 Comparison with Common Refrigerants

Comparison Item R31(this product) R22 R142B
CompositionSingle compound CH₂ClFSingle compound CHClF₂Single compound C₂H₃ClF₂
Boiling point-9.1 ℃-40.8 ℃-9.2 ℃
ODPapprox. 0.020.0550.065
GWP(100 years)approx. 918102310
Vapor Pressure(25 ℃)approx. 0.34 MPa1.044 MPaapprox. 0.35 MPa
Regulatory statusHCFC controlled, perquotaHCFC controlled, perquotaHCFC controlled, perquota
Mainusespecialityexisting installed basesystem servicingMedium temperature
supplyperordersmall-batchbulk supplyperquotabulk supply

5 Packaging Specifications

Package Type Specification Filling Ratio Valve Connection Application
disposable cylinder10 kg(customizable 5 kg / 20 kg)≤ 0.90 kg/LW21.8-14(customizable CGA / DIN)small-batch and
steel cylinder40 kg(customizable 100 kg)≤ 0.90 kg/LW21.8-14perorderbulk supply
cylinder palletMade to orderPer cylinderW21.8-14Itemdistribution
ISO ISO tankMade to orderper ISO tankISO tankconnectionand Transport

Filling Ratioper"", steel cylinderper.

6 Applications

  • See the Technical Data Sheet (TDS) for full specifications.
  • specialityLow temperature and researchtesting
  • (pharmaceutical, )

Equipment Compatibility & Charging Advice

  • HCFC classcontrolled, Procurement and quota and,.
  • Main, system and.
  • perorderbulk supply, use, quantity and.
  • recovery and, emissions;Disposal.
  • Storage and ventilation, leak detection and Protection, Inhalation and Skin contact.

7 Storage & Transport

  • Storage,, ventilation, 40 ℃, ignition source, heat source and.
  • steel cylinder, and,,, and.
  • Vapour, Spillagelow-lying areas, ventilation and.
  • and oxygen, and (,, )Flammable.
  • and, Low 0.05 MPa.
  • Transportper Danger, and,.

8 Safety & Handling

  • controlledHCFC classcontrolled, Procurement, Storage, and "Montreal Protocol"quota, records and.
  • asphyxiation andVapour, Spillagelow-lying areas, oxygen, ventilationoxygen(Low 19.5 %).
  • SpillageSpillageventilation,;;leak detection, open flamesleak detection.
  • Thermal decomposition riskrefrigerantopen flames or High temperature,, ventilation.
  • frostbite ProtectionLiquefied gasfrostbite, and;frostbite 40 ℃.
  • Inhalation andVapour, and, fresh airoxygen;Eye contact 15.

9 Quality Assurance & Shipping Documents

  • Batch COA, Purity( or ), Moisture, Acidity and Evaporation Residue.
  • Moisture, and Low temperature.
  • 12 months, Batch, No. and.
  • perthird-party test report(SGS / ), SDS Description REACH, RoHS.

10 Frequently Asked Questions

R31 What is it mainly used for?

R31 and speciality refrigerant, Main (pharmaceutical, and ), specialityLow temperature and research. Refrigerant and.

Procurement R31 ?

R31 HCFC classcontrolled, Procurement controlled and quota/, use Description., records.

R31 Can it replace R22 ?

. R31 Boiling point -9.1 ℃, and R22, controlled HCFC,. R22 system R407C, R407F or low-GWP R32, R452A.

R31 Shelf life?

steel cylinder, Storage, R31 Shelf Life 12 months. small-batch, perorder.

Disclaimer
Specificationdata Typical,;Parameter Batch COA. and, or or, equipment and Regulations.

| Reviewed by: | Approved by: | Hubei Zhongjin Fluorine Chemical Co., Ltd.

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