R1336mzz Refrigerant Technical Data Sheet
Technical Data Sheet(TDS) (E)-1,1,1,4,4,4-Hexafluoro-2-butene(HFO-1336mzz(E)) C₄H₂F₆(CF₃CH=CHCF₃, ) R1336mzz, and.
1 Product Identification
| Item | Value |
|---|---|
| Product Name | R1336mzz(E) Refrigerant |
| Chemical Name | (E)-1,1,1,4,4,4-Hexafluoro-2-butene（HFO-1336mzz(E)） |
| English Name | (E)-1,1,1,4,4,4-Hexafluoro-2-butene（HFO-1336mzz(E)） |
| Molecular Formula | C₄H₂F₆(CF₃CH=CHCF₃, ) |
| Molecular Weight | 164.05 |
| CAS Registry Number | 692878-73-8 |
| UN Number | 3163 |
| Transport Hazard Class | Class 2.2, non-flammable gas |
| ASHRAE Safety Classification | A1(Low toxicity, non-flammable) |
| Reference Basis | Manufacturer data; the batch COA governs |
Reference Basis: Compiled from manufacturer data (safety classification per GB/T 7778, ASHRAE 34 / ISO 817)
2 Physical & Chemical Properties
R1336mzz Typicaldata, system and,.
| Item | Typical Value |
|---|---|
| Appearance | Colorless, transparent liquefied gas |
| Odor | Slight ethereal odour |
| Boiling Point (101.3 kPa) | 7.5 ℃ |
| Freezing Point | Low -20 ℃ |
| Critical Temperature | approx. 130.2 ℃ |
| Critical Pressure | approx. 3.64 MPa |
| Critical Density | approx. 489 kg/m³ |
| Vapor Pressure(20 ℃, ) | approx. 164 kPa |
| Liquid Density(20 ℃) | approx. 1,290 kg/m³ |
| Vapour Relative density(=1) | approx. 5.3 |
| Liquid Specific Heat(25 ℃) | approx. 1.38 kJ/(kg K) |
| Water Solubility(20 ℃) | approx. 0.28 g/L |
| Auto-Ignition Temperature | None (non-flammable) |
| Flammability Limits in Air (vol.%) | Non-flammable |
| OEL (8 h TWA) | 400 ppm(per HFO-1336mzz data) |
| Ozone Depletion Potential (ODP) | 0 |
| Global warming potential (GWP) GWP(100 years) | approx. 2 |
| Atmospheric Lifetime | approx. 121 |
3 Quality Specifications & Test Methods
R1336mzz Parameter, Batch COA.
| Item | Parameter | Test Method |
|---|---|---|
| Appearance | Colourless and clear, free of suspended matter and mechanical impurities | Visual inspection |
| Purity | ≥ 99.80 % | Gas chromatography GC-FID |
| Moisture | ≤ 20 ppm | Karl Fischer coulometric method |
| Acidity( HCl ) | ≤ 0.1 ppm | Alkali absorption - potentiometric titration |
| Evaporation Residue | ≤ 0.01 % | Gravimetric method |
| Non-Condensable Gas | ≤ 1.5 % | Gas chromatography |
| (E/Z) | E ≥ 99.5 % | Gas chromatography |
4 Comparison with Common Refrigerants
| Comparison Item | R1336mzz(E)(this product) | R1234yf | R245fa |
|---|---|---|---|
| Composition | Single compound CF₃CH=CHCF₃(E ) | Single compound CF₃CF=CH₂ | Single compound CF₃CH₂CHF₂ |
| Boiling point | 7.5 ℃ | -29.4 ℃ | 15.1 ℃ |
| Critical Temperature | approx. 130.2 ℃ | approx. 87.3 ℃ | approx. 154.5 ℃ |
| Operating pressure(25 ℃ ) | approx. 0.16 MPa | approx. 0.70 MPa | approx. 0.16 MPa |
| ODP | 0 | 0 | 0 |
| GWP(100 years) | approx. 2 | < 1 | approx. 1,030 |
| ASHRAE Safety Classification | A1 (non-flammable) | A2L(Mildly flammable) | B1(Non-flammable) |
| Typical | High temperatureheat pump, ORC, foam blowing | air conditioning, Low commercial refrigeration | foam blowing, ORC, High temperatureheat pump |
| Current selection | fourth-generation refrigerant, controlled | Lowlow-GWP | Subject to quota phase-down, R1233zd |
5 Packaging Specifications
| Package Type | Specification | Filling Ratio | Valve Connection | Application |
|---|---|---|---|---|
| disposable cylinder | 10 kg | ≤ 1.40 kg/L | CGA 660 / DISS 716(perorder) | testing and supply |
| steel cylinder | 400 kg | ≤ 1.40 kg/L | CGA 660 / DISS 716 | Itemsupply |
| cylinder pallet | Made to order | Per cylinder | CGA 660 / DISS 716 | Itemdistribution |
| ISO ISO tank | approx. 15 t | per ISO tank | ISO tankconnection | Transport |
Filling Ratioper"", steel cylinderper.
6 Applications
- High temperatureheat pump and heat pump
- Organic Rankine Cycle(ORC)
- foam blowing and Low temperature cascade
- Semiconductorprocess
Equipment Compatibility & Charging Advice
- R1336mzz(E) Operating pressure R1234yf and R134a,, and per.
- Non-flammable, Low(ASHRAE A1), explosion-proof Special Requirements,.
- Boiling point 7.5 ℃,, and;Relative R1234yf, Low temperature.
- and, POE;system, and and refrigerant.
- ORC or heat pumpsystem, refrigerant, and system.
7 Storage & Transport
- Storage,, ventilation, 40 ℃, ignition source, heat source and.
- steel cylinder, and,,, and.
- 2.2 classNon-flammable, Accidental release measures equipment and ventilation.
- and oxygen, (,, ).
- and, Low 0.05 MPa.
- Transportper Danger 2.2 class, Firefighting, and.
8 Safety & Handling
- Flammability and explosion riskR1336mzz(E) A1 Non-flammable refrigerant, Risk.
- RiskOperating pressure HFC and HFO refrigerant,, charging and per.
- SpillageSpillageventilation,;Vapourheavier than air(approx. 5.3), low-lying areas and oxygen deficiency Risk.
- FirefightingNon-flammable, percarbon dioxide,, Firefighting;steel cylinder.
- frostbite Protectionor frostbite, and;frostbite 40 ℃.
- Inhalation andVapourasphyxiation and, fresh airoxygen;Eye contact 15.
9 Quality Assurance & Shipping Documents
- Batch COA, Purity( or ), Moisture, Acidity and Evaporation Residue.
- Moisture, and Low temperature.
- 12 months, Batch, No. and.
- perthird-party test report(SGS / ), SDS Description REACH, RoHS.
10 Frequently Asked Questions
R1336mzz(E) R1234yf What is the difference?
fourth-generation HFO refrigerant, ODP, GWP Low(approx. 2 and < 1), Non-flammable or Flammable.: R1336mzz(E) Boiling point 7.5 ℃, Operating pressure R1234yf -29.4 ℃, High temperature and ORC;R1234yf air conditioningLow.
R1336mzz(E) What risks come with high operating pressure?
Main and charging Risk. system R134a R1336mzz(E),,, compressor and, per.
R1336mzz(E) Is it a controlled substance?
. R1336mzz(E) ODP, GWP approx. 2, "Montreal Protocol"controlled Ozone-depleting substance, "Kigali Amendment"HFC control, quota, fourth-generation refrigerant and.
Disclaimer
Specificationdata Typical,;Parameter Batch COA. and, or or, equipment and Regulations.
Specificationdata Typical,;Parameter Batch COA. and, or or, equipment and Regulations.
| Reviewed by: | Approved by: | Hubei Zhongjin Fluorine Chemical Co., Ltd.
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